CHEM 6B Lecture Notes - Lecture 15: Conjugate Acid, Pennsylvania Route 14, Sarong

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03/09/2016 (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) When we put them together we can cross off both ch3co2 (aq) and both. If the ka is very big then the kb has to be very small and vice versa. This is the autoprotolysis of water so we have kw. Ch3co2h, and we end up with (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) because they have to equal a constant (kw= 1. 0x10-14) (cid:1) The weaker the acid the stronger the conj. Base or the stronger the acid the weaker the conj. Base (cid:1) pkw=pka +pkb= 14. 00 (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) Which of the following produces the strongest conj. A. hcn (pka=9. 31) since it has a biggest pka that means it is a: ch3co2h (pka= 4. 75, hclo (pka= 7. 53, hf (pka = 3. 45, hcooh (pka=3. 75) weak acid therefore it must have the strongest conj. Base (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) (cid:1)

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