CHEM 14B Lecture Notes - Lecture 3: Inert Gas, Chemical Reaction

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Change in concentration (k does not change) Chemical reaction at equilibrium represents a fixed. More product will form until original p/r ratio is. More reactant will form until original p/r ratio is attained (same k) attained (same k) Chemical reactions adjust so as to minimize the effect of changes (le chatelier"s principle) Without adding more reactants how would you increase yield of nh3. Le chatelier"s principle also applies to changing physical parameters: p & t. N2 + 3h2 2nh3 (all gas) Change in pressure (k does not change) V decreases and more moles of gas on left, then rxn shifts right left. V decreases and more moles of gas on right, then rxn shifts. If pressure of rxn vessel increased by adding inert gas, then moles of reactant, product and volume are constant. No change in r and p concentration and no effect on reaction.

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