Biology 1201A Lecture Notes - Lecture 14: Lone Pair, Oxyanion, Enol

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Keto-enol tautomerization: keto (double bonded o) and enol (double bonded carbons with an alcohol group attached to one of them are in equilibrium with each other. The oxygen is still double bonded (=o)to the adjacent carbon: in the oxyanion form, that lone pair makes a double bond with the adjacent carbon and pushes the electrons from our keto group onto the oxygen atom. Racemization: chiral center means it has 4 different r-groups attached. Krebs) go into either alcoholic fermentation (yeasts) or lactic acid fermentation (humans: next stage: krebs cycle aerobic (requires oxygen). Needs 2 atp, generates reduced e carriers: last state: electron transport chain aerobic. Glycolysis: investment phase: glucose is phosphorylated & converted to glyceraldehyde 3-phosphate, or. Requires 2 atp: payoff phase: gap molecules are oxidized to pyruvate. Each gap makes 2 atp (4 total) & an nadh: c6h12o6 + 2nad+ + 2atp + 4 adp + 2 pi. > 2 pyruvate + 2nadh + 2adp + 4 atp.

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