NUTR 3070 Lecture Notes - Lecture 4: Anomer, Reducing Sugar, Oligosaccharide

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Monosaccharides: most common is glucose, occur naturally, cannot be hydrolyzed into a small unit (simplest unit, considered a reducing sugar when the anomeric carbon is free. Disaccharides: most common is sucrose, two monosaccharides joined by an acetyl bond = glycosidic bond, determines whether we have the enzymes to break it down or not. Polysaccharides: homo- and hetero-polysaccharides, glycogen (animal, starch and cellulose (plant) All cho have a h:o ratio of 2:1. Why is it important biological systems are stereo-specific. Stereoisomerism same molecular formula and sequence, but differ in 3d space due to chiral carbon atoms. Chiral carbons carbons with four different atoms or groups. Diastereomers = not a mirror: exist in two forms: d vs. l, determined by the oh group on the highest chiral carbon, oh on the right = d, oh on the left = l. D-monosaccharides are nutritionally more important because digestive enzymes are stereo- specific for d sugars.

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