CHEM102 Lecture Notes - Lecture 19: Covalent Bond, Coordination Number, Electron Configuration

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CHEM102 Full Course Notes
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CHEM102 Full Course Notes
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General properties of transition metals, electron configuration and oxidation states: transition metals show similarities: Adding an extra core d e- does not affect the chemistry: trends (cid:858)across a period(cid:859): Atomic size decreases at first but then stays constant d electrons fill the inner shell and shield outer electrons, hence 4s electrons are not pulled closer. Electronegativity increases and then decreases: trends (cid:858)vertically(cid:859): Atomic size increases from period 4 to 5, but not from period 5 to 6. An increase in 32 protons shrinks the atom in period 6 which is roughly equal to the normal size increase when a new energy level is added. Atomic mass increases but volume changes are insignificant: general transition element properties: Most are paramagnetic (attracted by magnets: general difference in properties: Au, pt- no oxide formation: ground state configuration: [noble gas] ns2(n-1)dx. Period 6 and 7 include the f sub level.

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