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9 Nov 2021

Given information

The postulates of the kinetic theory that are not valid at high pressure and low temperature are

There is no force of attraction between the molecules of a gas.

Volume of the molecules of a gas is negligibly small in comparison to the space occupied by the gas.

Step-by-step explanation

Step 1.

At high pressures, PV increases above the ideal gas value because the first postulate of the kinetic theory of gases is no longer valid. As pressure increases, the molecules are squeezed close to one another, and the volume of the molecules themselves becomes a significant fraction of the volume of the container. Which violates the law

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